An iridium(III)-based lab-on-a-molecule for cysteine/homocysteine and tryptophan using triple-channel interrogation.

An iridium(III)-based lab-on-a-molecule for cysteine/homocysteine and tryptophan using triple-channel interrogation.
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DOI:
10.1039/c3an01530k
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发表时间:
2013-10
期刊:
The Analyst
影响因子:
--
通讯作者:
Kun Chen;M. Schmittel
Kun Chen;M. Schmittel
中科院分区:
其他
文献类型:
--
作者:
Kun Chen;M. Schmittel

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Ir络合物是一种分子实验室,用于识别和定量所有蛋白质来源氨基酸混合物中的半胱氨酸/同型半胱氨酸和色氨酸。UV-Vis和光致发光通道适合于水介质中同型半胱氨酸和半胱氨酸的定量,例如通过在606 nm处的发射增强,而色氨酸在电化学发光通道中被选择性地定量。
Iridium complex is a lab-on-a-molecule for recognising and quantifying cysteine/homocysteine and tryptophan in a mixture of all proteinogenic amino acids. UV-Vis and photoluminescence channels are suitable for quantification of homocysteine and cysteine in aqueous media, e.g. by emission enhancement at 606 nm, while tryptophan was selectively quantified in the electrochemiluminescence channel.