Effect of electronegativity on the mechanical properties of metal hydrides with a fluorite structure

Effect of electronegativity on the mechanical properties of metal hydrides with a fluorite structure
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DOI:
10.1016/j.jallcom.2006.02.036
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发表时间:
2006-12
影响因子:
6.2
通讯作者:
Masato Ito;D. Setoyama;J. Matsunaga;H. Muta;K. Kurosaki;M. Uno;S. Yamanaka
Masato Ito;D. Setoyama;J. Matsunaga;H. Muta;K. Kurosaki;M. Uno;S. Yamanaka
中科院分区:
材料科学2区
文献类型:
--
作者:
Masato Ito;D. Setoyama;J. Matsunaga;H. Muta;K. Kurosaki;M. Uno;S. Yamanaka

文献摘要

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Bulk titanium, yttrium, and zirconium hydrides, which have the same structure as that of fluorite-type fcc_C1, were produced and their mechanical properties were investigated. With an increase in the hydrogen content, the lattice parameters of titanium and zirconium hydrides increased, whereas those of yttrium hydride decreased. The elastic moduli of titanium and zirconium hydrides decreased by hydrogen addition, whereas those of yttrium hydride increased. There are linear relations between the electronegativities and hydrogen content dependence of the properties. Therefore, the mechanical properties of the metal hydrides are considered to be determined by a common rule based on the electronegativity.