In situ construction of metal–organic sulfur-containing heterocycle frameworks
In situ construction of metal–organic sulfur-containing heterocycle frameworks
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DOI：
10.1016/j.ccr.2010.09.011
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发表时间：
2011
影响因子：
20.6
通讯作者：
Hai‐Bin Zhu;S. Gou
中科院分区：
文献类型：
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作者：
Hai‐Bin Zhu;S. Gou
本文综述了构建金属-有机含硫杂环骨架的三种原位方法，即原位S-S功能反应、原位C-S键断裂和原位硫醇-S原子反应。每种方法都从三个方面进行了详细的描述，即(I)反应参数，(Ii)所涉及的有机转化和配位方式，(Iii)那些原位生成的金属配位化合物的迷人的结构和功能性质。
This review outlines three types of in situ methods used for constructing metal–organic sulfur-containing heterocycles frameworks, viz., in situ S–S function reactions, in situ C–S bond cleavage and in situ thiol-S atom reactions. Each method is described in detail in three respects, namely (i) reaction parameters, (ii) the organic transformation and coordination modes involved, and (iii) fascinating structures and functional properties of those in situ-generated metal-coordination compounds.