Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)
Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)
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DOI：
10.1039/c4cc08785b
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发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
McKenzie, Christine J.
中科院分区：
文献类型：
--
作者：
de Sousa, David P.;Bigelow, Jennifer O.;McKenzie, Christine J.
Cr(IV)eta(2)-过氧络合物在33% H2O2水溶液中结晶。该配合物可能是H2O2催化歧化的中间体，在溶液和固体状态下通过单一金属位点机制发生歧化。
A Cr(IV)eta(2)-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution - and solid state.