Evaluated kinetic and photochemical data for atmospheric chemistry
Evaluated kinetic and photochemical data for atmospheric chemistry
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DOI：
10.1063/1.555619
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发表时间：
1980
影响因子：
4.3
通讯作者：
D. L. Baulch;R. A. Cox;R. F. Hampson;J. Kerr;Jürgen Troe;R. T. Watson
中科院分区：
文献类型：
--
作者：
D. L. Baulch;R. A. Cox;R. F. Hampson;J. Kerr;Jürgen Troe;R. T. Watson
本文对中层大气化学（10-55公里高度）中性物质气相化学反应的动力学和光化学进行了严格评价。这项工作是由作者在CODATA化学动力学工作组的主持下进行的。已经为148个热反应和光化学反应编写了数据表，其中载有现有实验数据的摘要，并附有实验程序的详细说明。对于每个反应，在298 K下的速率系数的优选值连同温度依赖性（在可能的情况下）一起给出。讨论了优选值的选择，并对每一反应的速率系数和温度系数的精度进行了估计。数据表旨在提供所需的基本物理化学数据，作为模拟大气化学的计算的输入。提供了一个总结优选速率数据的表格，以及一个附录，列出了关于反应物和产物物质形成过程的可用数据。
This paper contains a critical evaluation of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in middle atmosphere chemistry (10–55 km altitude). The work has been carried out by the authors under the auspices of the CODATA Task Group on Chemical Kinetics. Data sheets have been prepared for 148 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each reaction a preferred value of the rate coefficient at 298 K is given together with a temperature dependency where possible. The selection of the preferred value is discussed, and estimates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction. The data sheets are intended to provide the basic physical chemical data needed as input for calculations which model atmospheric chemistry. A table summarizing the preferred rate data is provided, together with an Appendix listing the available data on enthalpies of formation of the reactant and product species.