An Extremely Bright Heteroleptic Bis(dipyrrinato)zinc(II) Complex
An Extremely Bright Heteroleptic Bis(dipyrrinato)zinc(II) Complex
复制标题
DOI：
10.1002/asia.201200131
复制
发表时间：
2012-05-01
影响因子：
4.1
通讯作者：
Nishihara, Hiroshi
中科院分区：
文献类型：
--
作者：
Kusaka, Shinpei;Sakamoto, Ryota;Nishihara, Hiroshi
让您的光芒闪耀：杂配双（二吡啶）锌 (II) 络合物的第一个例子 7a 是由两种类型的二吡啉合成的，通过 BODIPY 的新脱硼方案制备。配合物7a表现出比相应的均配配合物5a和6更高的荧光量子产率（在甲苯中为0.76）。7a作为发光团的优越性在极性较大的CH 2 Cl 2 中更加突出（见图）。
Let your light shine: The first example of a heteroleptic bis (dipyrrinato) zinc (II) complex, 7 a, was synthesized from two types of dipyrrins prepared by a new deboration protocol for BODIPYs. Complex 7 a showed a higher fluorescence quantum yield (0.76 in toluene) than the corresponding homoleptic complexes 5 a and 6. The superiority of 7 a as a luminophore was more prominent in more polar CH 2 Cl 2 (see picture).