Tunable Selectivity of Lanthanide Ion Exchange within a Coordination Polymer
Tunable Selectivity of Lanthanide Ion Exchange within a Coordination Polymer
复制标题
配位聚合物内稀土离子交换的可调选择性
DOI：
10.2116/analsci.29.685
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发表时间：
2013
影响因子：
1.6
通讯作者：
A. Wakisaka
中科院分区：
文献类型：
--
作者：
Yuiko Tasaki‐Handa;K. Ooi;Mikiya Tanaka;A. Wakisaka
研究了稀土离子（Ln^3+）在铈（III）或钐（III）离子与有机磷配体形成的配位聚合物（CP）与溶液之间的交换。CP表现出独特的Ln^3+亲和力，这种亲和力随其骨架的微小变化而变化，这取决于中心的Ln^3+。
The exchange of lanthanide(III) ions (Ln^3+) between a solution and a coordination polymer (CP) formed by cerium(III) or samarium(III) ion and an organophosphorous ligand has been studied. The CPs exhibit distinctive Ln^3+ affinity that varies with a small change in its framework, depending on the central Ln^3+.