A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs

A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs
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DOI:
10.1039/c3ce42162g
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发表时间:
2014
期刊:
影响因子:
3.1
通讯作者:
I. Boldog;K. V. Domasevitch;Jana K. Maclaren;C. Heering;Gamall Makhloufi;C. Janiak
I. Boldog;K. V. Domasevitch;Jana K. Maclaren;C. Heering;Gamall Makhloufi;C. Janiak
中科院分区:
化学3区
文献类型:
--
作者:
I. Boldog;K. V. Domasevitch;Jana K. Maclaren;C. Heering;Gamall Makhloufi;C. Janiak

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合成了三种基于金刚烷衍生的四面体四唑配体的多孔配位聚合物[M4(μ4-Cl)L2]·nGuest(M = Cu,Cd)。沿着一个已知的代表,行的化合物建立了一个新的等网格系列与萤石为基础的网络。
Three porous coordination polymers with a simplified formula of [M4(μ4-Cl)L2]·nGuest (M = Cu, Cd) based on two adamantane-derived tetrahedral tetrazolate ligands were synthesized. Along with one known representative, the row of compounds establishes a new isoreticular series with fluorite as the underlying net.