Rhodium(I)-catalyzed intramolecular Pauson-Khand reaction
Rhodium(I)-catalyzed intramolecular Pauson-Khand reaction
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DOI：
10.1021/om980410k
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发表时间：
1998-08-17
期刊：
影响因子：
2.8
通讯作者：
Sung, BK
中科院分区：
文献类型：
--
作者：
Jeong, N;Lee, S;Sung, BK
首次实现了铑（I）催化剂上的炔、烯烃和一氧化碳的共环化反应。与以前使用的后过渡金属相反，这些催化剂具有可调配体，使该反应更通用。
Cocyclization of alkynes, alkenes, and carbon monoxide by rhodium(I) catalysts was realized for the first time. Contrary to the previously employed late transition metals, these catalysts possess tunable ligands that make this reaction more versatile.