Investigation of U(VI) desorption behavior from natural sediment, Oak Ridge

Investigation of U(VI) desorption behavior from natural sediment, Oak Ridge
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橡树岭天然沉积物中 U(VI) 解吸行为的研究

DOI:
10.1007/s10967-017-5384-x
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发表时间:
2017-09
影响因子:
1.6
通讯作者:
Meng Ting
Meng Ting
中科院分区:
化学4区
文献类型:
--
作者:
Liu Hu;Cheng Wen;Wang Min;Meng Ting

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Investigation of U(VI) desorption from the natural sediment of Oak Ridge Field Research Center saprolite is of great importance to predict the fate and transport of U(VI) in the subsurface environment. After treatment by the dithonite- citrate-bicarbonate method, only 20% of U(VI) was extracted by 0.1 mol/L HNO3 solution, indicating that the predominate adsorbed carrier of U(VI) in natural sediment was iron (hydr)oxides. Further evidence collected through a high resolution TEM investigation such as goethite observed in clay minerals. The desorption of U(VI) from PRFRC saprolite was satisfactorily fitted by surface complexation modeling at a low NaHCO3 concentration starting from 0.001 to 0.1 mol/L, whereas appreciable over-estimation was observed at high concentrations of NaHCO3. The uncertainty analysis method used in this study was an expanded uncertainty analysis method, and estimates with a 95% confidence interval (c) were obtained for these test data points. These observations revealed that the goethite with clay minerals played the vital role in U(VI) sorption and desorption behaviors in subsurface sediments.
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