3D Printed Reactionware for Synthetic Electrochemistry with Hydrogen Fluoride Reagents
3D Printed Reactionware for Synthetic Electrochemistry with Hydrogen Fluoride Reagents
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DOI：
10.1002/celc.202100496
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发表时间：
2021-06-01
期刊：
影响因子：
4
通讯作者：
Lennox, Alastair J. J.
中科院分区：
文献类型：
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作者：
Heard, David M.;Doobary, Sayad;Lennox, Alastair J. J.
有机化合物的电化学还原反应经常使用腐蚀性的氟化氢试剂。由于这些试剂的腐蚀性，需要建造或购买对氟化氢稳定的电池，这需要高成本的材料、加工时间和专业知识。在这里，我们提供了一种使用3D打印的替代解决方案，这是一种廉价且快速的制造技术。我们已经设计，打印和共享四种不同的电池类型的聚丙烯和测试他们在电化学烯烃二氢化反应中存在的三乙胺3HF和吡啶聚（HF）。
Electrochemical fluorination reactions of organic compounds frequently employ hydrogen fluoride reagents that are corrosive. The corrosive nature of these reagents necessitates either the construction or purchase of cells that are stable to hydrogen fluoride, which require high-cost materials, machining time and expertise. Herein, we offer an alternative solution using 3D printing, which is an inexpensive and rapid manufacturing technique. We have designed, printed and shared four different cell types in polypropylene and tested them in an electrochemical alkene difluorination reaction in the presence of triethylamine 3HF and pyridinium poly (HF).