Water-dependent charge-transfer-induced spin transition of a prussian blue analog
Water-dependent charge-transfer-induced spin transition of a prussian blue analog
复制标题
普鲁士蓝类似物的水依赖性电荷转移诱导的自旋跃迁
DOI：
10.1039/c6dt03474h
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发表时间：
2016
影响因子：
4
通讯作者：
S. Hayami
中科院分区：
文献类型：
--
作者：
H. Ohmagari;R. Ohtani;M. Nakaya;M. Ohba;M. Nakamura;L. F. Lindoy;S. Hayami
钴铁普鲁士蓝类似物是一类具有电荷转移诱导自旋跃迁（CTIST）的磁性功能化合物，然而客体分子如水对磁性的影响尚不清楚。本文首次报道了Na_（0.46）Co [Fe（CN）_6]_（0.78）（H_2O）_（1.31）的水依赖CTIST行为及其单晶X射线结构分析。
Cobalt–iron Prussian blue analogues are magnetic functional compounds that exhibit charge-transfer-induced spin transition (CTIST), however, the role of guest species such as water in influencing the magnetic behaviour has remained unclear. Here, we report the water-dependent CTIST behaviour of Na0.46Co[Fe(CN)6]0.78(H2O)1.31 together with its single crystal X-ray structural analysis, for the first time.