Separation of polycyclic aromatic hydrocarbons by nonaqueous capillary electrophoresis using charge-transfer complexation with planar organic cations.
Separation of polycyclic aromatic hydrocarbons by nonaqueous capillary electrophoresis using charge-transfer complexation with planar organic cations.
复制标题
利用平面有机阳离子的电荷转移络合，通过非水毛细管电泳分离多环芳烃。
DOI：
10.1021/ac960734n
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发表时间：
1997
影响因子：
7.4
通讯作者：
Shea,D
中科院分区：
文献类型：
--
作者：
Miller,JL;Khaledi,MG;Shea,D
在这项研究中，我们研究了使用多环芳烃（PAHs）和平面有机阳离子之间的电荷转移相互作用在非水毛细管电泳。由于分离是在纯非水介质中进行的，因此该方法也便于分析在水或混合介质中溶解度低的溶质。在这项研究中提出的是多环芳烃的分离以及定量结构迁移关系，有助于实现更好地理解的力量，通过该多环芳烃分子与受体阳离子相互作用。研究发现，除了电荷转移相互作用外，静电力和分散力在PAH-阳离子结合中也发挥着重要作用。
In this study, we examine the use of charge-transfer interactions between polycyclic aromatic hydrocarbons (PAHs) and planar organic cations in nonaqueous capillary electrophoresis. Since the separations are performed in a purely nonaqueous medium, this method also facilitates the analysis of solutes that have low solubilities in aqueous or mixed media. Presented in this study are the separations of PAHs as well as the quantitative structure−migration relationships that assisted in achieving a better understanding of the forces through which the PAH molecules interact with the acceptor cation. It was found that, in addition to charge-transfer interactions, electrostatic and dispersive forces play an important role in PAH−cation binding.