Two-dimensional hopping motion of encapsulated La atoms in silylated La(2)@C(80).
Two-dimensional hopping motion of encapsulated La atoms in silylated La(2)@C(80).
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DOI：
10.1039/b703473c
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发表时间：
2007-06
影响因子：
4.9
通讯作者：
T. Wakahara;M. Yamada;Satomi Takahashi;T. Nakahodo;T. Tsuchiya;Y. Maeda;T. Akasaka;M. Kako;K. Yoza;E. Horn;N. Mizorogi;S. Nagase
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文献类型：
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作者：
T. Wakahara;M. Yamada;Satomi Takahashi;T. Nakahodo;T. Tsuchiya;Y. Maeda;T. Akasaka;M. Kako;K. Yoza;E. Horn;N. Mizorogi;S. Nagase
对La（2）@C（80）金属富勒烯的外配体功能化衍生物La（2）@ C（80）（Ar（2）Si）（2）CH（2）（：Ar = Mes，Mes = mesityl，：Ar = Dep，Dep = 2，6-diethylphenyl）的（139）La NMR研究表明，两个La原子沿着C（80）笼的赤道在两个位置之间跳跃.
The (139)La NMR study of the exohedrally functionalized derivatives of La(2)@C(80) metallofullerene, La(2)@C(80)(Ar(2)Si)(2)CH(2) (: Ar = Mes, Mes = mesityl, : Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C(80) cage.