Coordination chemistry of mononuclear ruthenium complexes bearing versatile 1,8-naphthyridine units: Utilization of specific reaction sites constructed by the secondary coordination sphere
Coordination chemistry of mononuclear ruthenium complexes bearing versatile 1,8-naphthyridine units: Utilization of specific reaction sites constructed by the secondary coordination sphere
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DOI：
10.1016/j.ccr.2017.11.024
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发表时间：
2017-12
影响因子：
20.6
通讯作者：
Dai Oyama;Ryosuke Abe;T. Takase
中科院分区：
文献类型：
--
作者：
Dai Oyama;Ryosuke Abe;T. Takase
本文回顾了单核钌配合物中以配体为中心的反应性领域的最新工作。讨论了聚吡啶衍生配体的配位化学，特别关注其源自氧化还原响应性 1,8-萘啶官能团的连接的以配体为中心的氧化还原特性。该综述提供了将复杂且多功能的 1,8-萘啶基配体纳入单核钌配合物的关键见解。
This article reviews recent work in the area of ligand-centered reactivities in mononuclear ruthenium complexes. The coordination chemistry of polypyridine-derived ligands is discussed, with particular focus on their ligand-centered redox properties originating from the attachment of redox-responsive 1,8-naphthyridine functional groups. This review provides key insights towards the incorporation of sophisticated and versatile 1,8-naphthyridine-based ligands into mononuclear ruthenium complexes.