Strain-modulated Ni3Al alloy promotes oxygen evolution reaction

Strain-modulated Ni3Al alloy promotes oxygen evolution reaction
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应变调制Ni3Al合金促进析氧反应

DOI:
10.1016/j.jallcom.2020.156094
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发表时间:
2020-12
影响因子:
6.2
通讯作者:
Hongyan Liang
Hongyan Liang
中科院分区:
材料科学2区
文献类型:
--
作者:
Mei Han;Shicheng Li;Chong Li;Jing Wu;Jingrui Han;Ning Wang;Yongchang Liu;Hongyan Liang

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Oxygen evolution reaction (OER) is crucial for electrochemical water splitting. However, corrosive issues in the alkaline environment impede its applications. Here, we explore the corrosion-resistant multiphase Ni3Al-based intermetallic alloy (Ni3Al alloy) as self-supported OER catalysts for the first time. A two-step treatment, annealing at high-temperature followed by acid oxidation is performed to improve the catalytic activity. Further investigations demonstrate that the annealing process can tune the size of γ′ precipitates, which will modify the strain effects caused by γ/γ′ lattice mismatch to boost the OER activity. The oxidation of Ni during the acid pretreatment can facilitate the formation of active high-valent Ni sites during the OER process, and further enhance the OER performance. The optimized electrode exhibits a low overpotential of 280 mV at 10 mA cm−2, a small Tafel slope of 73.5 mV dec−1and long-term stability of 180 h in 1 M KOH solution. The findings in this paper will inspire the exploration of high stability OER catalysts and the functional application of Ni3Al alloy.
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