A Simple and Effective Synthesis of Aryl Azides via Arenediazonium Tosylates
A Simple and Effective Synthesis of Aryl Azides via Arenediazonium Tosylates
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DOI：
10.1055/s-0033-1339648
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发表时间：
2013-10-01
影响因子：
2.6
通讯作者：
Parello, Joseph
中科院分区：
文献类型：
--
作者：
Kutonova, Ksenia V.;Trusova, Marina E.;Parello, Joseph
芳香族叠氮化合物是由芳香重氮对甲苯磺酸盐和叠氮化钠在室温下在水中高产率地生成，或由芳香胺在p-TsOH存在下通过重氮化生成的。除了实验简单之外，这些方法不需要任何金属催化，而且不需要纯化就能提供清洁的产品。
Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH. Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.