Crabtree's catalyst revisited; ligand effects on stability and durability.
Crabtree's catalyst revisited; ligand effects on stability and durability.
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DOI：
10.1039/b711979h
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发表时间：
2008-01
影响因子：
4.9
通讯作者：
Yingjian Xu;D. Mingos;John M. Brown
中科院分区：
文献类型：
--
作者：
Yingjian Xu;D. Mingos;John M. Brown
通过三聚体形成的单膦单胺铱氢化催化剂的时间依赖性失活的程度强烈依赖于配体结构;试图对抗该过程导致观察到耐低聚催化剂。
The extent of time-dependent deactivation of monophosphine monoamine iridium hydrogenation catalysts by trimer formation is strongly dependent on ligand structure; attempts to counter this process lead to the observation of an oligomerisation resistant catalyst.