Solid–liquid phase-transfer catalysis without solvent: selective mono- and di-alkylation of benzyl methyl ketone

Solid–liquid phase-transfer catalysis without solvent: selective mono- and di-alkylation of benzyl methyl ketone
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无溶剂固液相转移催化:苄基甲基酮的选择性单烷基化和二烷基化

DOI:
10.1039/p19920002427
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发表时间:
1992
期刊:
Journal of The Chemical Society-perkin Transactions 1
影响因子:
--
通讯作者:
P. Sánchez
P. Sánchez
中科院分区:
--
文献类型:
--
作者:
A. Aranda;A. Diaz;E. Díez;A. Hoz;Andrés Moreno;P. Sánchez

文献摘要

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苄基甲基酮1的烷基化是在无溶剂的情况下通过相转移催化进行的。通过通用、选择性和温和的条件,获得了单-2和二-烷基衍生物3和4的优异产率。
The alkylation of benzyl methyl ketone 1 has been performed by phase-transfer catalysis without solvent. Excellent yields of mono-2 and di-alkyl derivatives 3 and 4 were obtained through general, selective and mild conditions.