Pd(II)-catalyzed Formal O-H Insertion Reactions of Diazonaphthoquinones to Acetic Acid: Synthesis of 1,2-Naphthalenediol Derivatives
Pd(II)-catalyzed Formal O-H Insertion Reactions of Diazonaphthoquinones to Acetic Acid: Synthesis of 1,2-Naphthalenediol Derivatives
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DOI：
10.1246/cl.2011.1129
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发表时间：
2011-10-05
影响因子：
1.6
通讯作者：
Okauchi, Tatsuo
中科院分区：
文献类型：
--
作者：
Kitamura, Mitsuru;Kisanuki, Masato;Okauchi, Tatsuo
在Pd（II）催化下，重氮萘醌类化合物与乙酸进行了甲醛O-H插入反应，得到了1，2-萘并萘醌单乙酸酯。在卤化锂存在下，在此反应条件下得到卤代萘酚。
Pd(II)-catalyzed formal O-H insertion reaction of diazonaphthoquinones to acetic acid proceeded to afford 1,2-naphthalenediol monoacetates. In the presence of lithium halides, halonaphthols were obtained under the reaction conditions.