Enantiomerically Pure Chiral {Cu(II)32}-Based 2D-Layered Frameworks: From the Asymmetric Octacopper(II) Subcomponents to 3D Hierarchical Supramolecular Structures.
Enantiomerically Pure Chiral {Cu(II)32}-Based 2D-Layered Frameworks: From the Asymmetric Octacopper(II) Subcomponents to 3D Hierarchical Supramolecular Structures.
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DOI：
10.1021/acs.inorgchem.5b02654
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发表时间：
2016-03
影响因子：
4.6
通讯作者：
Wei-Wei Meng-Wei;Feng Xu;Weijian Xu
中科院分区：
文献类型：
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作者：
Wei-Wei Meng-Wei;Feng Xu;Weijian Xu
通过研究酒石酸盐配体、胍盐阳离子和金属之间的相互作用，合成了两种包含八铜(II)子组分的新型手性铜(II)配位聚合物。我们的分析证实，这些化合物是表现出 3D 分层超分子结构的对映体，该结构由 2D 亚层构成并通过非共价键相互作用维持。
Two new chiral copper(II) coordination polymers comprising octacopper(II) subcomponents were synthesized through investigation of the interplay among tartrate ligands, guanidinium cations, and metals. Our analysis confirms that these compounds are enantiomers exhibiting 3D hierarchical supramolecular structures that are constituted by 2D sublayers and sustained by noncovalent bonding interactions.