Physical Chemistry of Surfaces
Physical Chemistry of Surfaces
复制标题
DOI：
10.1007/978-3-642-67041-1_3
复制
发表时间：
1979
期刊：
影响因子：
--
通讯作者：
S. Yariv;H. Cross
中科院分区：
文献类型：
--
作者：
S. Yariv;H. Cross
胶体体系的行为主要受其较大的界面面积控制。界面被定义为构成胶体体系的相邻块体相之间的边界区域。当其中一个相是气体或蒸汽时，边界区域通常使用表面这一术语。表面热力学处理的基础是由吉布斯在上个世纪建立的，他在1878年发表了对该领域的相当大的贡献。他的工作仍然构成了现代热力学的基础(吉布斯，1928)。
The behavior of colloid systems is governed primarily by their largeinterfacial area. The interface is defined as the boundary region between the adjoining bulk phases that comprise the colloid system. When one of the phases is a gas or a vapor, the termsurfaceis commonly used for the boundary region. The foundation for thermodynamic treatment of surfaces was established in the last century by Gibbs, who published a considerable contribution to the field in 1878. His work still forms the basis of modern thermodynamics (Gibbs, 1928).