Zn(II)-catalyzed thiolysis of oxiranes in water under neutral conditions
Zn(II)-catalyzed thiolysis of oxiranes in water under neutral conditions
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DOI：
10.1021/jo0348266
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发表时间：
2003-10-17
影响因子：
3.6
通讯作者：
Vaccaro, L
中科院分区：
文献类型：
--
作者：
Fringuelli, F;Pizzo, F;Vaccaro, L
在30 ℃和pH 7.0的水中，各种1，2-环氧化物的硫解被ZnCl（2）（10 mol %）强烈加速，但使用氨基和羧基硫酚时除外。水介质和催化剂被回收并在各种运行中重复使用，而不影响该方法的效率。
Thiolysis of a variety of 1,2-epoxides in water at 30degreesC and pH 7.0 is strongly accelerated by ZnCl(2) (10 mol %) except when amino- and carboxythiophenol are used. The aqueous medium and the catalyst were recovered and reused in various runs without affecting the efficiency of the process.