Recent Developments in Carbocation and Onium Ion Chemistry
Recent Developments in Carbocation and Onium Ion Chemistry
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DOI：
10.1021/bk-2007-0965
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发表时间：
2007-07
期刊：
影响因子：
--
通讯作者：
K. Laali
中科院分区：
文献类型：
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作者：
K. Laali
前言第一章甲硅烷基取代碳正离子的实验和计算核磁共振波谱研究第二章-共轭阳离子通过双环骨架的加成第3章异常稳定的乙烯基阳离子第4章乙烯基碘鎓盐作为乙烯基阳离子的前体第5章由亚烷基环丙酮缩醛生成亚烷基烯丙基阳离子与亲核试剂反应的选择性第6章亚烷基烯丙基阳离子的构象研究环丁基甲基阳离子第7章持久性有机阳离子络合物：结构和反应性第8章相邻阳离子基团对亲电位点的活化第9章稳定的碳阳离子作为氧化还原活性发色团使用稳定的碳阳离子制备电致变色材料第10章阳离子池法和阳离子流法第11章芴亚基和茚亚基二价离子：第十二章生成、稳定性第13章表面上的碳阳离子通过在NAY沸石上环丙基羰基氯的电离形成双环丁鎓阳离子第14章分子轨道计算庚烷脱氢成甲苯反应中的正离子中间体第15章碳正离子结构和动力学的理论研究第16章氮杂多环芳烃氧化代谢产物碳正离子的量子化学研究第17章碳正离子的稳定性如何控制贝克曼重排反应？第18章溶剂对溴和溴碳正离子化学反应的影响第19章CFY 2+（Y = Cl，Br）和CX 3+（X = Cl，Br，OTeF 5）阳离子的合成使用稀有气体氧化剂XeOTeF 5 +Sb（OTeF 5）6？第20章有机氧鎓盐的“异脱硼”合成、反应性和NMR光谱性质第21章从双氨基卤鎓离子到受体烯烃的卤素转移反应：手性卤化反应的机理和策略第22章金属催化加成反应合成膦鎓盐
Foreword Preface Chapter 1 Experimental and computational NMR spectroscopic investigation of silyl-substituted carbocations Chapter 2 Super-Stabilization of -Conjugated Cations by Annelation to Bicyclic Frameworks Chapter 3 Unusually Stable Vinyl Cations Chapter 4 Vinyl Iodonium Salts as Precursors to Vinyl Cations Chapter 5 Generation of Alkylideneallyl Cations from Alkylidenecyclopropanone Acetals Selectivity of Reaction with Nucleophiles Chapter 6 Conformational Studies of Cyclobutylmethyl Cations Chapter 7 Persistent Organic Cationic Complexes: Structure and Reactivity Chapter 8 Activation of Electrophilic Sites by Adjacent Cationic Groups Chapter 9 Stabilized Carbocations as Redox Active Chromophores Preparation of Electrochromic Materials Using Stabilized Carbocations Chapter 10 Cation Pool Method and Cation Flow Method Chapter 11 Fluorenylidene and Indenylidene Dications: Insights about Antiaromaticity Chapter 12 Generation, Stability, and Reactions of Alkylated Fullerene Cations Chapter 13 Carbocations on Surfaces FORMATION OF BICYCLOBUTONIUM CATION VIA IONIZATION OF CYCLOPROPYLCARBINYL CHLORIDE OVER NAY ZEOLITE Chapter 14 MO Calculations involving -hydrido cation intermediates relevant to the heptane to toluene dehydrocyclization reaction Chapter 15 Theoretical Studies on Structure and Dynamics of Carbonium Ions Chapter 16 Quantum Chemical Studies of Carbocations from Oxidized Metabolites of Aza-Polycyclic Aromatic Hydrocarbons (Aza-PAHs) Chapter 17 How Does Carbocation Stability Control the Beckmann Rearrangement Reaction? Chapter 18 Solvent Effects on the Chemistry of Bromonium and -Bromo-carbenium Ions as Reactive Intermediates Chapter 19 Syntheses of the CFY2+ (Y = Cl, Br) and CX3+ (X = Cl, Br, OTeF5) Cations Employing the Noble-Gas Oxidant, XeOTeF5+Sb(OTeF5)6? Chapter 20 Organoxenonium Salts SYNTHESIS BY "XENODEBORYLATION", REACTIVITIES, AND NMR SPECTROSCOPIC PROPERTIES Chapter 21 Halogen transfer reactions from bis-amino halonium ions to acceptor olefins: mechanism and strategies for chiral halogenation Chapter 22 Synthesis of Phosphonium Salts by Metal-Catalyzed Addition Reaction