Large changes in hydricity as a function of charge and not metal in (PNP)M–H (de)hydrogenation catalysts that undergo metal–ligand cooperativity

Large changes in hydricity as a function of charge and not metal in (PNP)M–H (de)hydrogenation catalysts that undergo metal–ligand cooperativity
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DOI：
10.1039/d2cy01349e
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发表时间：
2023
期刊：
Catalysis Science & Technology
影响因子：
--
通讯作者：
Kevin Schlenker;Lillee K. Casselman;R. Vanderlinden;C. Saouma
Kevin Schlenker;Lillee K. Casselman;R. Vanderlinden;C. Saouma
中科院分区：
其他
文献类型：
--
作者：
Kevin Schlenker;Lillee K. Casselman;R. Vanderlinden;C. Saouma

文献摘要

相似文献

在经历金属 - 配体协同作用的（脱）氢催化剂中，配体的pKa和金属的氢负离子亲和势（hydricity）相互关联，与金属或配体的特性无关。阴离子型氢化物的氢负离子性质比其中性对应物显著更强。
Ligand pKa and metal hydricity scale with one another in (de)hydrogenation catalysts that undergo metal–ligand cooperativity, irrespective of metal or ligand identity. Anionic hydrides are significantly more hydridic than their neutral counterparts.