[Mn(CO)4{S2CNMe(CH2CO2H)}], a new water-soluble CO-releasing molecule
[Mn(CO)4{S2CNMe(CH2CO2H)}], a new water-soluble CO-releasing molecule
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DOI：
10.1039/c1dt10125k
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发表时间：
2011-01-01
影响因子：
4
通讯作者：
Motterlini, Roberto
中科院分区：
文献类型：
--
作者：
Crook, Sian H.;Mann, Brian E.;Motterlini, Roberto
[Mn(CO)(4){S2CNMe(CH2CO2H)}]，1是一个释放CO的分子，每摩尔化合物至少提供3个CO摩尔。CO损失的机理是解离的和可逆的，并用Gaussian09计算进行了研究。CO的可逆结合导致化合物的相对稳定的溶液，而在CO受体或配体的存在以防止CO的重新结合时，CO迅速丢失。确定了其X-射线结构。
[Mn(CO)(4){S2CNMe(CH2CO2H)}], 1, is shown to be a CO releasing molecule providing at least three moles CO per mole of compound. The mechanism of CO loss is dissociative and reversible and was investigated using Gaussian 09 calculations. The reversible binding of CO results in a relatively stable solution of the compound, while in the presence of a CO receptor or a ligand to prevent the rebinding of CO, the CO is lost rapidly. The X-ray structure was determined.