Fast, long-range electron-transfer reactions of a 'blue' copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer
Fast, long-range electron-transfer reactions of a 'blue' copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer
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DOI：
10.1039/b312936e
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发表时间：
2004-02-07
影响因子：
4.9
通讯作者：
Webster, GR
中科院分区：
文献类型：
--
作者：
Armstrong, FA;Barlow, NL;Webster, GR
通过在金电极上原位皂化二苯乙烯基硫代乙酸酯形成的自组装单分子层（SAM），在超过15埃的距离上与吸附的“蓝色”铜蛋白——天青蛋白分子实现了快速电子转移（ET）（零驱动力下的交换速率超过1600 s⁻¹）。
A self-assembled monolayer (SAM), formed by the in situ saponification of a stilbenyl thioacetate on a gold electrode, yields fast electron transfer (ET) (the exchange rate at zero driving force exceeds 1600 s(-1)) with adsorbed molecules of the 'blue' copper protein, azurin, over a distance exceeding 15 Angstrom.