Photoredox-Catalyzed Cyclopropanation of Michael Acceptors
Photoredox-Catalyzed Cyclopropanation of Michael Acceptors
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DOI：
10.1002/ejoc.201601604
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发表时间：
2017-04-18
影响因子：
2.8
通讯作者：
Garcia Suero, Marcos
中科院分区：
文献类型：
--
作者：
del Hoyo, Ana M.;Garcia Suero, Marcos
本文报道了一种光氧化还原催化α，β-不饱和羰基化合物与二碘甲烷环丙烷化反应的新方法。该转化的特征在于其温和的条件、官能团相容性和优异的选择性。
A new protocol for the catalytic cyclopropanation of alpha,beta-unsaturated carbonyl compounds with diiodomethane by means of photoredox catalysis has been successfully developed. The transformation is characterized by its mild conditions, functional-group compatibility, and excellent selectivity profile.