Recent Progress in the Design of Advanced Cathode Materials and Battery Models for High‐Performance Lithium‐X (X = O2, S, Se, Te, I2, Br2) Batteries
Recent Progress in the Design of Advanced Cathode Materials and Battery Models for High‐Performance Lithium‐X (X = O2, S, Se, Te, I2, Br2) Batteries
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DOI：
10.1002/adma.201606454
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发表时间：
2017-05
影响因子：
29.4
通讯作者：
Jiantie Xu;Jianmin Ma;Qinghua Fan;Shaojun Guo;Shixue Dou
中科院分区：
文献类型：
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作者：
Jiantie Xu;Jianmin Ma;Qinghua Fan;Shaojun Guo;Shixue Dou
新型Li-X(X=O2，S，Se，Te，I2，Br2)电池正极材料的最新进展和成就为高性能锂离子电池替代品的开发提供了新的机遇。本文综述了近年来发展高性能Li-X(X=O2，S，Se，Te，I2，Br2)电池正极材料和电池模型的重要进展。我们从简要介绍开始，解释为什么Li-X电池对未来的可再生能源设备很重要。然后，我们总结了锂-O2(S)电池正极材料发展中存在的缺陷、主要进展和新出现的挑战。对于新兴的Li-X(Se、Te、I2、Br2)电池，我们系统地总结了它们的优缺点和最新进展。具体地说，我们综述了采用不同电极制造技术的碳酸盐/乙醚基电解液制成的锂硒(Te)电池以及不同电池设计(如双电解液、全有机电解液、有/无阴极流模式以及燃料电池/太阳能电池一体化)的Li-I2(Br2)电池的电化学性能。最后对前景广阔的Li-X(X=O2，S，Se，Te，I2，Br2)电池正极材料的发展前景和面临的挑战进行了展望。
Recent advances and achievements in emerging Li‐X (X = O2, S, Se, Te, I2, Br2) batteries with promising cathode materials open up new opportunities for the development of high‐performance lithium‐ion battery alternatives. In this review, we focus on an overview of recent important progress in the design of advanced cathode materials and battery models for developing high‐performance Li‐X (X = O2, S, Se, Te, I2, Br2) batteries. We start with a brief introduction to explain why Li‐X batteries are important for future renewable energy devices. Then, we summarize the existing drawbacks, major progress and emerging challenges in the development of cathode materials for Li‐O2 (S) batteries. In terms of the emerging Li‐X (Se, Te, I2, Br2) batteries, we systematically summarize their advantages/disadvantages and recent progress. Specifically, we review the electrochemical performance of Li‐Se (Te) batteries using carbonate‐/ether‐based electrolytes, made with different electrode fabrication techniques, and of Li‐I2 (Br2) batteries with various cell designs (e.g., dual electrolyte, all‐organic electrolyte, with/without cathode‐flow mode, and fuel cell/solar cell integration). Finally, the perspective on and challenges for the development of cathode materials for the promising Li‐X (X = O2, S, Se, Te, I2, Br2) batteries is presented.