Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review
Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review
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DOI：
10.1016/s1352-2310(03)00391-1
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发表时间：
2003-01-01
影响因子：
5
通讯作者：
Arey, J
中科院分区：
文献类型：
--
作者：
Atkinson, R;Arey, J
大量的非甲烷有机化合物从生物源排放到大气中，主要来自植被。这些有机化合物包括异戊二烯、C10 H16单萜、C15 H24倍半萜和许多含氧化合物，包括甲醇、己烯衍生物、2-甲基-3-丁烯-2-醇和6-甲基-5-庚烯-2-酮。在对流层中，这些有机化合物与羟基（OH）自由基、硝酸根（NO3）自由基和臭氧（O-3）反应，在对流层低层的化学中起着重要作用。本文介绍并简要讨论了生物有机化合物对流层反应的动力学、产物和机理。(C)2003 Elsevier Ltd.保留所有权利。
Large quantities of non-methane organic compounds are emitted into the atmosphere from biogenic sources, mainly from vegetation. These organic compounds include isoprene, C10H16 monoterpenes, C15H24 sesquiterpenes, and a number of oxygenated compounds including methanol, hexene derivatives, 2-methyl-3-buten-2-ol, and 6-methyl-5-hepten-2-one. In the troposphere these organic compounds react with hydroxyl (OH) radicals, nitrate (NO3) radicals and ozone (O-3), and play an important role in the chemistry of the lower troposphere. In this article the kinetics, products and mechanisms of the tropospheric reactions of biogenic organic compounds are presented and briefly discussed. (C) 2003 Elsevier Ltd. All rights reserved.