Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids
Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids
复制标题
铱催化仲烯丙醇与羧酸的区域和对映选择性烯丙酯化
DOI：
10.1039/d1cc04861a
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发表时间：
2021
影响因子：
4.9
通讯作者：
Sun Jiangtao
中科院分区：
文献类型：
--
作者：
Tang Shengbiao;Zhang Peng;Wang Changkai;Shao Ying;Sun Jiangtao
本文报道了一种以游离酸为亲核剂，在温和的反应条件下，红外催化的外消旋仲烯丙醇的不对称烯丙酸酯化反应，具有广泛的官能团耐受性，表现出良好的区域和对映体选择性。
We report herein an iridium-catalyzed asymmetric allylic esterification of racemic secondary allylic alcohols using free carboxylic acids as nucleophiles under mild conditions with broad functional group tolerance, exhibiting excellent regio- and enantioselectivity .