Ni-induced supramolecular structural transformation of cytosine on Au(111): from one-dimensional chains to zero-dimensional clusters.

Ni-induced supramolecular structural transformation of cytosine on Au(111): from one-dimensional chains to zero-dimensional clusters.
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DOI:
10.1039/c3cc49241a
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发表时间:
2014-02
影响因子:
4.9
通讯作者:
Huihui Kong;Likun Wang;Qinggang Tan;Chi Zhang;Qiang Sun;W. Xu
Huihui Kong;Likun Wang;Qinggang Tan;Chi Zhang;Qiang Sun;W. Xu
中科院分区:
化学2区
文献类型:
--
作者:
Huihui Kong;Likun Wang;Qinggang Tan;Chi Zhang;Qiang Sun;W. Xu

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高分辨STM成像和DFT计算的相互作用表明,通过引入Ni原子,胞嘧啶在Au(111)表面的自组装结构发生了从一维链状到一维团簇的结构转变。有趣的是,形成的0-D团簇分别分布在表面上。
Interplay between high-resolution STM imaging and DFT calculations demonstrates that through introduction of Ni atoms the self-assembled structures of cytosine could undergo a structural transformation from 1-D chains to 0-D clusters on Au(111). Interestingly, the 0-D clusters formed are separately distributed on the surface.