The chiral recognition of guest molecules in trio-o-thymotide clathrates: A semi-empirical approach. Preliminary communication†
The chiral recognition of guest molecules in trio-o-thymotide clathrates: A semi-empirical approach. Preliminary communication†
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三邻胸腺肽包合物中客体分子的手性识别：一种半经验方法†。
DOI：
10.1002/hlca.19800630645
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发表时间：
1980
影响因子：
1.8
通讯作者：
J. Allemand
中科院分区：
文献类型：
--
作者：
R. Gerdil;J. Allemand
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The enantiomers of a chiral solvent can be enclathrated to a different extent in a crystal lattice consisting of tri-o-thymotide (1) molecules of a given handedness. This property affords a mean of studying the stereoselective interaction of a chiral environment with an enclosed chiral component. The general approach to account for the observed differences in stereoselectivity is based on the calculation and comparison of the minimum energies for the respective inclusion of enantiomeric guest molecules within a rigid cage of given chirality. An interpretation of the fair chiral recognition of 2-bromobutane as opposed to the unselective inclusion of 2-butanol is attempted.