Reaction of NaP5 with half-sandwich complexes of nickel:: The first example of an Ni-promoted transformation of the P5- anion
Reaction of NaP5 with half-sandwich complexes of nickel:: The first example of an Ni-promoted transformation of the P5- anion
复制标题
DOI：
10.1021/om050078u
复制
发表时间：
2005-04-25
期刊：
影响因子：
2.8
通讯作者：
Hey-Hawkins, E
中科院分区：
文献类型：
--
作者：
Miluykov, V;Kataev, A;Hey-Hawkins, E
五磷杂环戊二烯钠NaP 5与[Cp*NiBr（PPh 3）]（CP* = eta（5）-C5 Me 5）的反应仅产生分解产物。然而，与[（eta（3）-C3 Ph 3）NiBr（PMe 2 Ph）]形成1，2-二磷杂环戊二烯钠，其是不寻常的镍促进的五磷杂环戊二烯阴离子降解的产物。
The reaction of sodium pentaphosphacyclopentadienide, NaP5, with [Cp*NiBr(PPh3)] (CP* = eta(5)-C5Me5) gave only decomposition products. However, with [(eta(3)-C3Ph3)NiBr(PMe2Ph)] sodium 1,2-diphosphacyclopentadienide was formed, which is the product of an unusual Ni-promoted degradation of the pentaphosphacyclopentadienide anion.