Extension of the eschenmoser sulfide contraction iminoester cyclization method to the synthesis of tolyporphin chromophore

Extension of the eschenmoser sulfide contraction iminoester cyclization method to the synthesis of tolyporphin chromophore
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DOI:
10.1016/s0040-4039(97)01601-8
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发表时间:
1997-09-29
影响因子:
1.8
通讯作者:
Kishi, Y
Kishi, Y
中科院分区:
化学4区
文献类型:
--
作者:
Minehan, TG;Kishi, Y

文献摘要

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用Eschenmoser硫化物缩合/亚氨基酯缩合法制备的八氢卟啉前驱体28经双醛缩合反应合成了Tolyporphin发色团2。(C)1997年爱思唯尔科学有限公司。
Tolyporphin chromophore 2 has been synthesized by performing a double-retroaldol/oxidation sequence on an octahydroporphyrin precursor 28 prepared by using the Eschenmoser sulfide-contraction/iminoester-condensation method. (C) 1997 Elsevier Science Ltd.