Reaction of frustrated Lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond.
Reaction of frustrated Lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond.
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DOI：
10.1002/anie.201101051
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发表时间：
2011-07
影响因子：
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通讯作者：
Bao‐Hua Xu;G. Kehr;R. Fröhlich;B. Wibbeling;B. Schirmer;S. Grimme;G. Erker
中科院分区：
文献类型：
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作者：
Bao‐Hua Xu;G. Kehr;R. Fröhlich;B. Wibbeling;B. Schirmer;S. Grimme;G. Erker
受挫，但不沮丧：受挫的刘易斯对（FLP）可以与共轭炔酮进行选择性的1，4-加成反应（见示意图）。在FLP二氢活化时，可以实现碳-碳三键的选择性氢化，在一种情况下甚至是催化性的。
Frustrated, but not frustrating: Frustrated Lewis pairs (FLPs) can undergo selective 1, 4-addition reactions with conjugated ynones (see scheme). Upon FLP dihydrogen activation selective hydrogenation of the carbon-carbon triple bond can be achieved, in one case even catalytically.