Spontaneous resolution of an axially dissymmetric 3-carbamoylpyridinium iodide; intrinsic discrimination between the enantiomeric forms by the introduction of a second chiral element
Spontaneous resolution of an axially dissymmetric 3-carbamoylpyridinium iodide; intrinsic discrimination between the enantiomeric forms by the introduction of a second chiral element
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轴向不对称 3-氨基甲酰碘化吡啶的自发拆分；
DOI：
10.1039/c39860000536
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发表时间：
1986
期刊：
影响因子：
--
通讯作者：
Hm Henk Buck
中科院分区：
文献类型：
--
作者：
L. A. M. Bastiaansen;J. Kanters;F. H. V. D. Steen;J. A. C. D. Graaf;Hm Henk Buck
3-[N-甲基-N-(R)-α-甲基苄基]氨基甲酰-1,2,4-三甲基碘化吡啶鎓固体酰胺旋转异构体中的羰基取向方向由酰胺侧链中的(R)-手性决定；结构，通过 X 射线分析和 c.d. 确定。谱，是相关的。
The direction of the carbonyl-orientation in a solid amide-rotamer of 3-[N-methyl-N-(R)-α-methylbenzyl]carbamoly-1,2,4-trimethylpyridinium iodide is governed by the (R)-chirality in the amide side chain; structures, as determined by X-ray analysis and c.d. spectra, are correlated.