Versatile hybridization of conjugated polymers with silica
Versatile hybridization of conjugated polymers with silica
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DOI：
10.1039/c1jm13150h
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发表时间：
2011-09
影响因子：
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通讯作者：
Y. Morisaki;Y. Tsuji;Y. Chujo
中科院分区：
文献类型：
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作者：
Y. Morisaki;Y. Tsuji;Y. Chujo
本文介绍了一种在共轭聚合物（如刚性棒PAE）存在下，通过普通溶胶-凝胶反应制备共轭聚合物/SiO_2杂化材料的简单方法。PAE的酰胺侧链和残余硅烷醇基团之间的氢键导致PAE在SiO2基质中的有效分散，即使在不存在增容剂的情况下。
A simple method for preparing a conjugated-polymer/SiO2 hybrid by the common sol–gel reaction in the presence of a conjugated polymer such as a rigid-rod PAE is described. Hydrogen bonding between amide side chains of the PAE and residual silanol groups leads to effective dispersion of the PAE in the SiO2 matrix even in the absence of a compatibilizer.