Pd(0)-Catalyzed amphiphilic activation of bis-allyl alcohol and ether
Pd(0)-Catalyzed amphiphilic activation of bis-allyl alcohol and ether
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DOI：
10.1021/ja0479787
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发表时间：
2004-09-15
影响因子：
15
通讯作者：
Kimura, M
中科院分区：
文献类型：
--
作者：
Mukai, R;Horino, Y;Kimura, M
Pd（0）·Et 3B催化对称烯丙基二醇1的两亲性活化，促进醛α位亲电烯丙基化和醛CO亲核烯丙基化，得到3-亚甲基环戊醇2，从而由市售二醇1生成两性离子三亚甲基甲烷物种。
Pd(0)·Et3B catalyzes amphiphilic activation of symmetric allylic diol1to promote electrophilic allylation at the α-position of aldehydes and nucleophilic allylation at the aldehyde CO, furnishing 3-methylenecyclopentalols2and thus generation of a zwitterionic trimethylenemethane species from the commercially available diol1.