One-step synthesis of the vicinal dinitroguaianolides achillin and grossmisin
One-step synthesis of the vicinal dinitroguaianolides achillin and grossmisin
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DOI：
10.1023/b:conc.0000003417.79920.8d
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发表时间：
2003-07-01
影响因子：
0.8
通讯作者：
Adekenov, SM
中科院分区：
文献类型：
--
作者：
Alebastrov, OV;Raldugin, VA;Adekenov, SM
以愈创木酚内酯的氯仿溶液为原料，通过鼓泡气态亚硝基氯合成1,10-二氢- 1,10-二硝基葛米辛。用x射线测定了分子结构。研究发现，含二氧化氮的NOCl可以加速类似硝酸盐的形成。
1,10-Dihydro-1alpha,10alpha-dinitrogrossmisin was synthesized by bubbling gaseous nitrosyl chloride through a chloroform solution of the guaianolide grossmisin. The molecular structure was determined by X-ray. It was found that the formation of similar dinitrates is accelerated by using NOCl containing nitrogen dioxide.