Assembly of hydrogen bonded diamondoid networks based on synthetic metal-organic tetrahedral nodes.
Assembly of hydrogen bonded diamondoid networks based on synthetic metal-organic tetrahedral nodes.
复制标题
DOI：
10.1021/ic048648q
复制
发表时间：
2005-01
影响因子：
4.6
通讯作者：
B. Ma;Haoling Sun;Song Gao
中科院分区：
文献类型：
--
作者：
B. Ma;Haoling Sun;Song Gao
Mn(ClO4)2 或 Co(PF6)2 与 4,4'-二吡啶二氧化物 (dpdo) 的反应产生了新型分子物种 [M(dpdo)4(H2O)2]2+，尽管金属中心周围有八面体环境，但其仍保持四面体构型。四面体部分通过 dpdo 配体的外围 NO 末端和配位水分子之间的氢键进一步组装，形成 3D 类金刚石网络。
Reaction of Mn(ClO4)2 or Co(PF6)2 with 4,4'-dipyridine-dioxide (dpdo) produced novel molecular species [M(dpdo)4(H2O)2]2+, which hold a tetrahedral configuration notwithstanding their octahedral environment around the metal centers. The tetrahedral moieties are further assembled through hydrogen bonds between peripheral NO ends of dpdo ligands and coordinated water molecules, giving rise to 3D diamondoid networks.