Liquid Crystals with Polar Substituents Containing Fluorine: Synthesis and Physical Properties

Liquid Crystals with Polar Substituents Containing Fluorine: Synthesis and Physical Properties
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含氟极性取代基液晶的合成与物理性质

DOI:
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发表时间:
1991
期刊:
影响因子:
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通讯作者:
U. Finkenzeller
U. Finkenzeller
中科院分区:
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文献类型:
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作者:
E. Bartmann;D. Dorsch;U. Finkenzeller

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已经制备了具有各种含氟极性端基的液晶化合物(参见下式1,其中Z = S <$CHF 2、S <$CF 3、SO <$CHF 2、SO <$CF 3、SO 2 <$CHF 2、SO 2 <$CF 3、SO 2 F、OCH 2 CF 3、CO <$OCH 2 CF 3、CO <$CF 3、CO <$CF 2 Cl、CO <$CF 2 H、CO <$CF 2 <$CH 3、CO <$CF 2 <$C3 H 7)。这些化合物的合成概述在这里和它们的物理性质(相变,介电各向异性,双折射,粘度)进行了讨论。
Abstract Liquid crystalline compounds with various polar terminal groups containing fluorine have been prepared (see below formula 1 with Z = S‒CHF2, S‒CF3, SO‒CHF2, SO‒CF3, SO2‒CHF2, SO2‒CF3, SO2F, OCH2CF3, CO‒OCH2CF3, CO‒CF3, CO‒CF2Cl, CO‒CF2H, CO‒CF2‒CH3, CO‒CF2‒C3H7). The synthesis of these compounds is outlined here and their physical properties (phase transitions, dielectric anisotropy, birefringence, viscosity) are discussed.