Porous lanthanide-organic framework with zeolite-like topology.
Porous lanthanide-organic framework with zeolite-like topology.
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DOI：
10.1039/b500971e
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发表时间：
2005-05
影响因子：
4.9
通讯作者：
T. Maji;G. Mostafa;Ho‐Chol Chang;S. Kitagawa
中科院分区：
文献类型：
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作者：
T. Maji;G. Mostafa;Ho‐Chol Chang;S. Kitagawa
以多功能4,5-咪唑二羧酸（imidc）为连接剂，水热合成了Ln(III), {[Ln2(imidc)2(H2O)3](H2O)}n, [Ln = Gd(III)(1)和Er(III)(2)]两种新型同构多孔骨架；它们具有类似沸石的网络拓扑结构，可以在脱水时提供另一种形式，并且对H2O、N2、CO2和MeOH具有选择性吸附特性。
Two novel isomorphous porous frameworks of Ln(III), {[Ln2(imidc)2(H2O)3](H2O)}n, [Ln = Gd(III) (1) and Er(III) (2)] have been synthesized hydrothermally using multifunctional 4,5-imidazoledicarboxylic acid (imidc) as a connector; they have a zeolite-like network topology which can provide another form upon dehydration, and exhibit selective adsorption properties for H2O over N2, CO2 and MeOH.