Pore partition effect on gas sorption properties of an anionic metal-organic framework with exposed Cu2+ coordination sites.

Pore partition effect on gas sorption properties of an anionic metal-organic framework with exposed Cu2+ coordination sites.
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DOI:
10.1039/c1cc14118j
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发表时间:
2011-09
影响因子:
4.9
通讯作者:
Yanxi Tan;Yan-Ping He;Jian Zhang
Yanxi Tan;Yan-Ping He;Jian Zhang
中科院分区:
化学2区
文献类型:
--
作者:
Yanxi Tan;Yan-Ping He;Jian Zhang

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本文提出了一种具有可移动客体阳离子的阴离子纳米孔框架材料,该材料可以与不同的四烷基铵阳离子进行离子交换,并且由此产生的可调孔结构在气体储存和分离方面表现出有趣的孔分配效应。
Presented here is an anionic nanoporous framework material with mobile guest cations which can perform ion exchanges with different tetraalkylammonium cations, and the resulting tunable pore structures exhibit interesting pore partition effects on gas storage and separation.