Location of the Yttrium Atom in Y@C82 and Its Influence on the Reactivity of Cage Carbons
Location of the Yttrium Atom in Y@C82 and Its Influence on the Reactivity of Cage Carbons
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DOI：
10.1021/ja905001w
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发表时间：
2009-09-02
影响因子：
15
通讯作者：
Nagase, Shigeru
中科院分区：
文献类型：
--
作者：
Lu, Xing;Nikawa, Hidefumi;Nagase, Shigeru
Y@C-82的第一个单晶结果明确地揭示了钇原子位于沿C-2轴的六方环下，这使得C-2v-C-82的24个非等效碳中只有1个与亲电试剂adamantylidene carbene充分反应，只产生两个单加合异构体。
The first single-crystallographic results of Y@C-82 unambiguously disclosed that the yttrium atom is located under a hexagonal ring along the C-2 axis, which makes only 1 out of 24 nonequivalent carbons of the C-2v-C-82 sufficiently reactive toward the electrophile adamantylidene carbene, affording only two monoadduct isomers.