Catalytic activation of nitrogen derivatives with transition-metal complexes
Catalytic activation of nitrogen derivatives with transition-metal complexes
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DOI：
10.1351/pac200678020363
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发表时间：
2006-02-01
影响因子：
1.8
通讯作者：
Lectard, S
中科院分区：
文献类型：
--
作者：
Lebel, H;Leogane, O;Lectard, S
介绍了过渡金属催化的含氮衍生物的Curtius重排反应和氮杂环戊二烯的生成，氮杂环戊二烯的C-H插入反应和氮杂环丙烷化反应。这些过程导致以高水平的选择性和效率形成C-N键。
Studies regarding the transition-metal-catalyzed decomposition of nitrogen derivatives toward Curtius rearrangement and the formation of nitrenes which undergo C-H insertion and aziridination reactions are presented. These processes lead to the formation of C-N bond with a high level of selectivity and efficiency.