Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis.
Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis.
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DOI：
10.1039/c6cc01944g
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发表时间：
2016-05
影响因子：
4.9
通讯作者：
Lei Zhu;Liansheng Wang;Bojie Li;Boqiao Fu;Cheng‐Pan Zhang;Wei Li
中科院分区：
文献类型：
--
作者：
Lei Zhu;Liansheng Wang;Bojie Li;Boqiao Fu;Cheng‐Pan Zhang;Wei Li
We report herein a single component Ir photoredox catalyst which is capable of catalyzing the hydrotrifluoromethylation of terminal alkenes and Michael acceptors with sodium triflinate (Langlois reagent) in methanol under irradiation at room temperature. Various synthetically useful functional groups, including ester, amide, ether, aldehyde, sulfone, ketone and aryl boronate, are well tolerated in this reaction.
