Low-temperature fluorination of ruthenium oxide fluorides
Low-temperature fluorination of ruthenium oxide fluorides
复制标题
氧化氟化钌的低温氟化
DOI：
10.1016/s0022-1139(00)84403-6
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发表时间：
1989
影响因子：
1.9
通讯作者：
R. Bougon
中科院分区：
文献类型：
--
作者：
L. Meublat;M. Lance;R. Bougon
研究了在HF溶液中，用氟化剂F2、ClF 3和KrF 2对RuO 2和RuO 4的氟化反应，发现KrF 2能与RuO 4反应生成四氟化钌RuOF 4。用元素分析、X-射线粉末衍射和红外吸收光谱对所制得的氟化钌进行了表征，并给出了有关RuO_2的分解结果。
The fluorination of the ruthenium oxides RuO2and RuO4was investigated by using the fluorinating agents F2, ClF3, or KrF2in HF solution.Among the most noticeable results, KrF2was found to be powerful enough to react with RuO4and to transform it into ruthenium oxide tetrafluoride RuOF4. This oxide fluoride of ruthenium VI so prepared was characterized by elemental analysis, X-ray powder diffraction and infrared absorption spectroscopy.Results concerning the fluorination of RuO2are also presented.