Ionothermal synthesis of a new (4,12)-connected heterometallic iodoplumbate with [Pb4(OH)4] cubane as joint points of the helices
Ionothermal synthesis of a new (4,12)-connected heterometallic iodoplumbate with [Pb4(OH)4] cubane as joint points of the helices
复制标题
DOI：
10.1039/c0ce00651c
复制
发表时间：
2011
期刊：
影响因子：
3.1
通讯作者：
Feilong Hu;Q. Zhai;Shu’ni Li;Yucheng Jiang;Mancheng Hu
中科院分区：
文献类型：
--
作者：
Feilong Hu;Q. Zhai;Shu’ni Li;Yucheng Jiang;Mancheng Hu
以溴化1-乙基-3-甲基咪唑鎓为溶剂，制备了异金属碘铅酸盐的第一个离子型配合物[CuPb_2I_2Br（OH）_2]（1）。它表现出前所未有的（4，12）-连接拓扑结构，[Pb 4（OH）4]立方烷作为螺旋的连接点。
The first ionothermal case of the heterometallic iodoplumbate, [CuPb2I2Br(OH)2] (1), was prepared using 1-ethyl-3-methyl imidazolium bromide as a solvent. It exhibits an unprecedented (4,12)-connected topology with [Pb4(OH)4] cubane as the joint points of the helices.