Crystallization in poly(n‐octadecyl methacrylate) monolayers
Crystallization in poly(n‐octadecyl methacrylate) monolayers
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聚（甲基丙烯酸正十八烷基酯）单层结晶
DOI：
10.1002/pol.1966.160040409
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发表时间：
1966
期刊：
影响因子：
--
通讯作者：
R. Matuura
中科院分区：
文献类型：
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作者：
T. Nakahara;K. Motomura;R. Matuura
研究了聚甲基丙烯酸十八酯在空气-水界面上的结晶动力学。结晶的速率已通过在不同温度和表面压力下单分子膜的面积随时间的减少来测量。结晶等温线已被分析的相变动力学的一般数学处理，结果表明线性增长占主导地位。通过引入平衡压力-面积等温线定义的过饱和度的差异说明了速率常数随温度和压力的变化。
The crystallization kinetics of poly(n-octadecyl methacrylate) has been studied at the air–water interface. The rate of the crystallization has been measured by the decrease in the area of monolayers with time at various temperatures and surface pressures. The crystallization isotherms have been analyzed by the general mathematical treatment of the kinetics of phase changes, and the results show linear growth to be dominant. The variation of the rate constant with temperature and pressure has been illustrated by the difference in the supersaturation defined by introducing the equilibrium pressure-area isotherms.